Valency and Bonding 1st Edition (PDF)

Valency and Bonding

Author:
Frank Weinhold & Clark R. Landis
Release at: 2005
Pages: 761
Edition:
First Edition
File Size: 10 MB
File Type: pdf
Language: English



Description of Valency and Bonding 1st Edition (PDF)

Valency and Bonding written by Frank Weinhold & Clark R. Landis is a great Chemistry book for chemical bonding studies available in (PDF) download. In identifying the features that distinguish this book from many predecessors, we do not attempt to conceal the enormous debt of inspiration owed to such classics as Pauling’s Nature of the Chemical Bond and Coulson’s Valence. We aspire neither to supplant these classics nor to alter substantially the concepts they expounded. Rather, our goal is to take a similarly global view, but develop a more current and quantitative perspective on valency and bonding concepts such as hybridization, electronegativity, and resonance, capitalizing on the many advances in wavefunction calculation and analysis that have subsequently occurred. We hope thereby to sharpen, revitalize, and enhance the usefulness of qualitative bonding concepts by presenting a “twenty-first-century view” of the nature of chemical bonding.

This graduate-level text presents the first comprehensive overview of modern chemical valency and bonding theory, written by internationally recognized experts in the field. The authors build on the foundation of Lewis- and Pauling-like localized structural and hybridization concepts to present a book that is directly based on current ab initio computational technology.

The presentation is highly visual and intuitive throughout, being based on the recognizable and transferable graphical forms of natural bond orbitals (NBOs) and their spatial overlaps in the molecular environment. The book shows applications to a broad range of molecular and supramolecular species of organic, inorganic, and bioorganic interest. Hundreds of orbital illustrations help to convey the essence of modern NBO concepts in a facile manner for those with no extensive background n the mathematical machinery of the Schr ̈odinger equation. This book will appeal to those studying chemical bonding in relation to chemistry, chemical engineering, biochemistry, and physics.




Content of Valency and Bonding 1st Edition (PDF)


Chapter 1: Introduction and theoretical background

  • The Schr ̈odinger equation and models of chemistry
  • Hydrogen-atom orbitals
  • Many-electron systems: Hartree–Fock and correlated treatments
  • Perturbation theory for orbitals in the Hartree–Fock framework: the donor-acceptor paradigm
  • Density matrices, natural localized and delocalized orbitals, and the Lewis-structure picture
  • Natural resonance structures and weightings
  • Pauli-exchange antisymmetry and steric repulsions
  • Summary
  • Notes for Chapter 1
  • Chapter 2: Electrostatic and ionic bonding

  • Introduction
  • Atomic and ionic orbitals
  • Charge transfer and hybridization in ionic bonding
  • Donor–acceptor theory of hybridization in ionic bonding
  • Ionic–covalent transitions
  • Ion–dipole and dipole–dipole bonding
  • Bent ionic compounds of heavy alkaline earth
  • Ionic bonding in d-block elements
  • Summary
  • Notes for Chapter 2
  • Chapter 3: Molecular bonding in s/p-block elements

  • Introduction
  • Covalent and polar covalent bonding
  • Conjugation and aromaticity
  • Hyperconjugation
  • Hypervalency: 3c/4e “ω bonds”
  • Hypovalency: 3c/2e bridge bonds
  • Summary
  • Notes for Chapter 3
  • Chapter 4: Molecular bonding in the d-block elements

  • Introduction
  • Lewis-like structures for the d-block elements
  • Hybridization and molecular shape
  • Covalent and polar-covalent bonding
  • Coordinative metal-ligand bonding
  • Beyond sigma bonding: transition-metal hyper bonding and pi back/front bonding
  • Hypovalency, agostic interactions, and related aspects of catalytic activation at metal centers
  • Hyperconjugative effects
  • Multielectron coordination
  • Vertical trends in transition-metal bonding
  • Localized versus delocalized descriptions of transition-metal bonding and hyper bonding
  • Summary
  • Notes for Chapter 4
  • Chapter 5: Supramolecular bonding

  • An introductory overview of intermolecular forces
  • Hydrogen bonding
  • Charge-transfer complexes
  • Transition-state species
  • Coupling of intramolecular and intermolecular interactions
  • Summary
  • Notes for Chapter 5
  • Appendix A. Methods and basis sets

    Appendix B. Chemical periodicity

    Appendix C. Units

    Index

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